Long-lasting Cu-based oxygen carrier material for industrial scale in Chemical Looping Combustion

Syngas combustion in a 500 Wth Chemical-Looping Combustion system using an impregnated Cu-based oxygen carrier

Chemical-Looping Combustion (CLC) is an emerging technology for CO2 capture because separation of this gas from the other flue gas components is inherently to the process and thus no energy is expended for the separation. For its use with coal as fuel in power plants, a process integrated by coal gasification and CLC would have important advantages for CO2 capture. This paper presents the combu...

Solid waste management of a chemical-looping combustion plant using Cu-based oxygen carriers.

Waste management generated from a Chemical-Looping Combustion (CLC) plant using copper-based materials is analyzed by two ways: the recovery and recycling of the used material and the disposal of the waste. A copper recovery process coupled to the CLC plant is proposed to avoid the loss of active material generated by elutriation from the system. Solid residues obtained from a 10 kWth CLC proto...

Reduction kinetics of CoO-NiO/Al2O3 oxygen carrier for chemical-looping combustion

This communication reports the reduction mechanism and kinetics of CoO-NiO/Al2O3 oxygen carrier using methane as the reduction gas. Kinetics experiments are performed in a novel fluidized bed CREC riser simulator under turbulent fluidized bed reaction conditions. A shrinking-core model is used for the kinetic modeling assuming spherical grains of the oxygen carrier particles. The XRD analysis s...

Ni-Cu OXYGEN CARRIERS TO REACH ZERO CO AND H2 EMISSIONS IN CHEMICAL-LOOPING COMBUSTION

Chemical looping combustion process in fixed - bed reactors using ilmenite as oxygen carrier

A process scheme based on a series of fixed-bed reactors is presented as a possible alternative for carrying out the chemical looping combustion of methane at high pressure with ilmenite as oxygen carrier. The oxygen carrier is stationary and it is alternately exposed to reducing and oxidizing atmospheres by means of the periodic switching of the gas feeds (i.e., methane and air, respectively)....